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紫外线吸收剂是一种光稳定剂,能选择性地强烈吸收对聚合物有害的太阳光及荧光光源中的紫外线部分,而本身具有高耐光性的有机化合物。按其结构可分为水杨酸酯类、二苯甲酮类、苯并三唑类、取代丙烯腈类、三嗪类等,由于实用的光稳定剂还需同时满足多方面其他性能要求,因此工业上应用最多的为二苯甲酮类和苯并三唑等类型的邻羟基芳香化合物。邻羟基芳香化合物紫外线吸收剂可形成分子内氢键螯合环,其耐光性来自于他们能通过非常快速的激发态分子内质子转移和高效无辐射去活过程进行可逆酚式-醌式互变异构转换循环,从而有效的将激发能转化为无害的热能。
Ultraviolet absorbent is a kind of light stabilizer, which can selectively and strongly absorb the ultraviolet part of the sun light and fluorescent light source harmful to polymer, and has high light resistance. According to its structure, it can be divided into salicylic acid esters, diphenylketones, benzotriazoles, substituted acrylonitrile, triazines, etc. Because practical photostabilizers need to meet other performance requirements at the same time, the most widely used in industry are o-hydroxyl aromatic compounds, such as diphenylketones and benzotriazoles. The UV absorbers of o-hydroxyl aromatic compounds can form intramolecular hydrogen bond chelating ring, and their light resistance comes from their ability to carry out reversible phenol-quinone-tautomerism conversion cycle through very fast excited intramolecular proton transfer and efficient irradiated deactivation process, thus effectively converting excitation energy into harmless thermal energy.
淬灭剂指通过分子间的能量转移(长程能量转移和接触或碰撞或交换能量转移两种),迅速而有效地将激发态分子(单线态氧和三线态物质)淬灭,使转变成热能或转变成荧光或磷光,而辐射散失,回到基态的一类物质,通过这一过程,使其免遭紫外线破坏,从而达到稳定高分子材料的目的。猝灭剂主要是金属络合物,如二价镍络合物等,常和紫外线吸收剂并用起协同作用。因此,它有别于紫外线吸收剂(并不强烈吸收紫外线),且作用机理也不同于紫外线吸收剂(通过分子内的结构变化转移能量),如常用镍的有机化合物--UV1084,中文别名为2,2-硫代双(4-叔辛基苯酚)正丁胺镍盐。
Quanching agent is a kind of material which through intermolecular energy transfer (long-term energy transfer and contact or collision or exchange energy transfer), quickly and effectively to excited state molecules(singlet and triplet state substances) quenching and converted into heat energy or into a fluorescence or phosphoresence, and radiation loss, return to the ground state. It can protect it from ultraviolet radiation and stabilize polymer material through this process. Most of quenching agents are metal complexes, such as divalent nickel complex, and often used with ultraviolet absorbent, to play a synergistic role. Therefore, it is different from ultraviolet absorbent (which does not strongly absorb ultraviolet radiation), and its mechanism of action is different from that of ultraviolet absorbent (Transfer energy through intramolecular structural change). For example, UV 1084, which is known as 2, 2-thio-bis (4-tert-octyl phenol) n-butylamine nickel salt in Chinese.
OMNISTAB UV 1084主要应用于聚乙烯棚膜、农膜,不仅具有抗紫外线辐射的作用,而且具有抗氧化剂的功能,具有较高的耐农药、耐酸性,在聚丙烯、聚乙烯纤维、人造草坪等领域具有广泛应用。它属于淬灭剂类光稳定剂,能够有效转移聚合物中生色基团激发态能量并将其以无害的形式消散掉从而使聚合物免于光降解反应。
OMNISTAB UV 1084 is mainly used in polyethylene film and agricultural film. It not only has the function of anti-ultraviolet radiation, but also has the function of anti-oxidant. It has a high resistance to pesticides and acid, and is widely used in polypropylene, polyethylene fiber, artificial lawn and other fields. It is a kind of light stabilizer which belong to quenching agent, which can effectively transfer the excited state energy of the chromogenic groups in the polymer and dissipate it in a harmless form, thus making the polymer immune to photodegradation.
OMNISTAB UV 1084着色性小对聚烯烃染料有螯合作用,可改善染色性,毒性低,对皮肤刺激性小,对常在高温下使用或长期经受日晒的制品尤为适宜。也可以与其他形式的稳定剂很好的配合使用尤其是紫外线吸收剂类产品。与聚烯烃产品具有极强的兼容性。使用在聚乙烯农用薄膜和聚丙烯人造草坪上具有极高的稳定性。
OMNISTAB UV 1084 has a small staining property, It chelates polyolefin dyes, it can improve dyeing properties, has low toxicity, and is less irritating to the skin. It is particularly suitable for products that are often used at high temperatures or subjected to prolonged exposure to the sun.It also works well with other forms of stabilizers, especially UV absorbers. It has strong compatibility with polyolefin products. It has high stability when used in polyethylene agricultural film and polypropylene artificial lawn.
此外,在PVC农膜中, UV 1084经常与DHT产品配合使用。DHT是一种卤素净化剂,可以有效吸收PVC在加工和使用过程中分解产生的HCL,提高PVC的热稳定性。而且DHT的含水率低,具有与烯烃相近的折射率,对透明烯烃的薄膜来说是非常适合的卤素净化剂。UV 1084搭配DHT一起使用时会产生长期的耐气候性。
In addition, in PVC agricultural film, UV 1084 is often used with DHT products. DHT is a halogen purifying agent, which can effectively absorb HCL generated by decomposition of PVC during processing and operating, and improve the thermal stability of PVC. In addition, DHT has a low water content and a similar refractive index to olefin, which makes it a very suitable halogen purifier for transparent olefin films. When we use UV1084 and DHT together, they produce long-term climate resistance.
更多产品细节,请参考产品技术说明书。青岛德达志成化工有限公司是一家专业生产和销售各类紫外线吸收剂、光稳定剂和高端抗氧剂的公司,致力于为您提供一站式的添加剂服务。更多详细信息,欢迎电话咨询我司销售团队!
For more details, please refer to the product specification. DELTACHEM(QINGDAO)CO., LTD is a professional manufacturer and distributor of various ultraviolet absorbent, light stabilizer and high-end antioxidant, committed to providing one-stop additive service for you. For more details, please call our sales team!